Library / Journals / Wiley / Applied Organometallic Chemistry
Copyright © 2009 John Wiley & Sons, Ltd.
TABLE OF CONTENTS
Volume 23 Issue 3 , Pages 91 - 133 (March 2009)
Full Papers
Characteristic reactions of group 9 transition metal compounds in organic synthesis (p 91-107)
Iwao Omae
Published Online: Feb 16 2009 4:03AM
DOI: 10.1002/aoc.1480
Group 9 metal compounds are widely utilized two characteristic reactions in organic synthesis. The first type reactions include Pauson-Khand reactions, the Pauson-Khand-type reactions, the other cyclizations, and coupling reactions. The second type ones include hydroformylations, the carbonylations of methanol, amidocarbonylations, and other carbonylations. | |
Synthesis and characterizations of N,N
-bis(diphenylphosphino)-2-(aminomethyl)aniline derivatives: application of a palladium(II) complex as pre-catalyst in Heck and Suzuki cross-coupling reactions (p 108-113)
Murat Aydemir, Ak
n Baysal, Gül
en Öztürk, Bahattin Gümgüm
Published Online: Dec 29 2008 3:53AM
DOI: 10.1002/aoc.1477
Metal complexes {Pd(II), Pt(II) and Cu(I)} and oxidation products of N,N | |
-bis(diphenylphosphino)-2-(aminomethyl)aniline, [Ph2PNHC6H4-CH2NHPPh2] 1 have been prepared and characterized. The catalytic behaviour of the Pd(II) complex was investigated in the Suzuki coupling and Heck reactions. Highly efficient bimetallic iron-palladium catalyzed Michael-type Friedel-Crafts reactions of indoles with chalcones (p 114-118)
Yue-Hua Gao, Lei Yang, Wei Zhou, Li-Wen Xu, Chun-Gu Xia
Published Online: Dec 29 2008 3:54AM
DOI: 10.1002/aoc.1478
Iron-palladium is a superior bimetallic catalyst in the presence of acetylacetone (Acac) with remarkable synergistic effect for the Michael-type Friedel-Crafts reactions of indoles with chalcones. This catalytic system has the advantages of mild reaction conditions, smaller amount of metal salts, high yields of the desired products and operational simplicity, which make it a useful and promising process for the synthesis of indole derivatives. | |
Metal and solvent-free cyanosilylation of carbonyl compounds with tris(pentafluorophenyl)borane (p 119-123)
Santosh T.adam, Sung Sooim
Published Online: Dec 19 2008 7:41AM
DOI: 10.1002/aoc.1479
A highly effective metal and solvent-free method of the cynaosilylation of aldehydes andetones with TMSCN in the presence of catalytic amount of B(C6F5)3 was developed. Various alehydes andetones were converted into the corresponding trimethylsilylether within short reaction times with excellent yield under mild conditions. | |
Synthesis and molecular structures of 1-chloro-1-silacyclopent-2-enes. Combination of 1,2-hydroboration, 1,1-organoboration and protodeborylation (p 124-131)
Ezzathan, Rhettempe, Bernd Wrackmeyer
Published Online: Jan 20 2009 11:18AM
DOI: 10.1002/aoc.1482
The consecutive 1,2-hydroboration and 1,1-organoboration of alkyn-1-yl(chloro)(methyl)vinyl- and alkyn-1-yl(chloro)(phenyl)vinylsilane with 9-borabicyclo[3.3.1]nonane (9-BBN) led selectively to 1-silacyclopent-2-ene derivatives containing a Si | |
Cl function. Protodeborylation with acetic acid left the SiBook Reviews
John Emsley. Better looking, better living, better loving. How Chemistry can help you achieve life's goals Wiley-VCH, May 2007, 237 pp. (hardcover). ISBN-10 3-527-31863-1; ISBN-13 978-3-527-31863-6 (p 132)
Peter Craig
Published Online: Feb 16 2009 4:04AM
DOI: 10.1002/aoc.1467
Ernesto Fattorusso and Orazio Tagialatela-Scafati (Eds). Modern alkaloids - structure, isolation, synthesis and biology Wiley-VCH; October 2007, 665 pp. ISBN 978-3-527-31521-5 (hardcover) (p 133)
Randolph Arroo
Published Online: Feb 16 2009 4:04AM
DOI: 10.1002/aoc.1468